“Metal Complexes” Science-Research, January 2022 — summary from NASA Technology Transfer Program, Astrophysics Data System, DOAJ, DOE Pages and Zenodo

NASA Technology Transfer Program — summary generated by Brevi Assistant

NASA Kennedy Space Center is seeking partners interested in the industrial application of the Activated Metal Treatment System for dealing with polychlorinated biphenyls in paints. Existing physical elimination approaches have the ability to remove PCB having paint from surfaces; nonetheless, these techniques usually develop a new waste stream that should be dealt with according to Toxic Substances Control Act regulation. NASA Langley Research Center has established a technique for the synthesis of fiber-metal laminates by radio regularity plasma spray deposition. The use of radio regularity plasma spray deposition provides a special approach to the construction of FMLs with many benefits. NASA has developed a novel hybrid supercapacitor system making use of vertical graphene as an electrode material expanded straight on enthusiast steels using a plasma enhanced chemical vapor deposition. The secret to the hybrid supercapacitor technology is the growth of vertical graphene directly on to a cost-effective metal substrate without making use of mass graphene, catalysts, or binders, resulting in increased power thickness. Pioneers at the NASA Johnson Space Center in collaboration with a vehicle companion have created the Modular Robotic Vehicle. NASA’s Langley Research Center has created a new strategy to enable the prep work of metal/composite hybrid laminates, known as fiber metal laminates, by transferring metal directly onto textile making use of a plasma deposition process. Exhaustion endurance is crucial for the airworthiness of army and civilian aging airplanes and for long-duration flights and deep space missions. The MMC consists of both shape memory alloy supports and some low-melting phase parts which, when warmed, essentially clamp the crack borders back together and flow material right into the split’s space for a high strength repair.

Please keep in mind that the text is machine-generated by the Brevi Technologies’ Natural language Generation model, and we do not bear any responsibility. The text above has not been edited and/or modified in any way.

Source texts:

Astrophysics Data System — summary generated by Brevi Assistant

The coumarin core is a recurring theme in both artificial and all-natural compounds that exhibit a wide range of biological properties including anticoagulant, anti-inflammatory, antioxidant, antiviral, antimicrobial and anticancer agents in addition to enzyme preventions. Electrocatalytic acetylene semihydrogenation is an encouraging option to thermocatalytic acetylene hydrogenation because of its ecological benignity and economic effectiveness, however its efficiency is far listed below that of the thermocatalytic reaction as a result of strong competition from side reactions, including hydrogen overhydrogenation, advancement and carbon-carbon coupling responses. Even in a crude ethylene feed containing 1 % acetylene, N-heterocyclic carbene-copper pays for a specific selectivity of > 99 % during a 100-h security examination, continuous ethylene production with only ~30 ppm acetylene, a big space speed of up to 9. 6 × 10 5 mL. In the present study, a collection of Schiff base by-products of pregabalin are complex with zinc and copper, and characterized by organic assays and spectroscopic methods. In the present research, unique metal complexes with an amino acid based bidentate imine ligand originated from thiophene-2carboxaldehyde and L-glutamine have been developed theoretically making use of DFT calculations and effectively synthesized experimentally. The vibrational spectroscopic research study of L-Threonine and Cd 2 facility are carried out under Raman, SERS, FTIR and UV-Vis spectroscopic strategies. The interaction mechanism of L-Threonine and Cd 2 complicated with the most effective binding sites of 1SJ0 and 3FUZ healthy protein receptors have been analysed under the molecular docking tool. Three new lanthanide complexes were manufactured by conventional remedy synthesis at area temperature level with the formula of [Ln 2] · H 2 O, [Ln 3 terpy] 2 · 2 · 2H 2 O,. The examination shows that complex 3 gives off a solid thumbs-up.

Please keep in mind that the text is machine-generated by the Brevi Technologies’ Natural language Generation model, and we do not bear any responsibility. The text above has not been edited and/or modified in any way.

Source texts:

DOAJ — summary generated by Brevi Assistant

Just recently, mono- and dinuclear complexes have been in the rate of interest of scientists because of their prospective application in other Medicinal not natural chemistry entailing the use of metal-based substances as therapeutics has come to be an area revealing distinct guarantee. Metal complexes trigger DNA crosslinking, leading to the inhibition of DNA synthesis and fixing. We report the development of hefty antacids metal complexes of bicyclic host molecules including the caesium complicated that catches the central metal ion with the deep pocket of the host similar to a baseball handwear cover. A combination of H4L1,2 and RbOH permitted seclusion of the mononuclear rubidium facility in which the metal center is six-coordinated in a loose style, the remaining two oxygen donors in the crown loophole and 2 phenols in the calix rim are unskillful. A new azo dye ligand 2- [2'-azo] -4ethoxyphenol was prepared by reacting a diazonium chloride salt solution of 2-amino-6methoxy benzothiazole and coupled with 4-ethoxy phenol in an alkaline ethanolic solution. Nevertheless, in vitro anticancer and poisoning of ligand and Pt-Complex were assessed by MTT cytotoxicity assay versus lung cancer cells cell line and normal human umbilical vein endothelial cells. Complexes of change steels [Co, Cd and Mo] With a new enaminone 3-chloro-4pent-3en-2one were manufactured and afterwards characterized by 1H NMR, 13C NMR, FAB-MS, UV- Vis, FTIR, icp-oes and tga. Evaluation of the cytotoxicity suggested that, the Co complicated has even more cytotoxic impact than enaminone ligand and various other complexes when evaluated on the human cancer cell lines MCF-7. Large-bite, bisphosphine, 2,6-bis-pyridine on treatment with [Mo24], [Ni22] And [MCl2] [M = Pd, Pt] Afforded corresponding chelate complexes [2,6-PPh2C3H2N22C5H3NMo4], [2,6-PPh2C3H2N22C5H3NNi2] And [2,6-PPh2C3H2N22C5H3NMCl2] [5, M = Pd; 6, M = Pt] Therapy of BDIP with one matching of [RuCl2] 2 caused a dinuclear facility [2,6-PPh2C3H2N22C5H3NRuCl22].

Please keep in mind that the text is machine-generated by the Brevi Technologies’ Natural language Generation model, and we do not bear any responsibility. The text above has not been edited and/or modified in any way.

Source texts:

  • https://doi.org/10.3390/ma14247783 — DFT TD-DFT Framework of Mixed-Metal Complexes with Symmetrical and Unsymmetrical Bridging Ligands — Step-By-Step Investigations: Mononuclear, Dinuclear Homometallic, and Heterometallic for Optoelectronic Applications.
  • https://doi.org/10.1055/s-0041-1741035 — Metal Complexes as DNA Synthesis and or Repair Inhibitors: Anticancer and Antimicrobial Agents.
  • https://doi.org/10.1107/S2052252521010563 — Regioisomers of singly bridged calix[6]crown-6 and their heavy alkali metal complexes: a molecular baseball glove for caesium(I).
  • https://doi.org/10.1016/j.rechem.2021.100245 — Synthesis, spectral characterization, antimicrobial evaluation studies and cytotoxic activity of some transition metal complexes with tridentate (N,N,O) donor azo dye ligand.
  • https://doi.org/10.1016/j.arabjc.2021.103640 — Thermal and spectroscopic studies of some metal complexes with a new enaminone ligand 3-chloro-4-((4-methoxyphenyl)amino)pent-3-en-2-one and their investigation as anti-urease and cytotoxic potential drugs.
  • https://doi.org/10.1016/j.rechem.2021.100161 — Transition metal complexes of imidazole appended pyridyline linked bisphosphine, 2,6-bis(2-(diphenylphosphanyl)-1H-imidazol-1-yl)pyridine.

DOE Pages — summary generated by Brevi Assistant

A series of alkali metal cerium diphenylhydrazido complexes, M x y [Ce 4], M = Li, Na, and K, x = 4 or 5, and y = 4, 8, or 7, were synthesized to probe just how an additional sychronisation ball would modulate digital structures at a cerium cation. Oxidation of the cerium diphenylhydrazido complex to the Ce diphenylhydrazido one was achieved with a basic cation exchange reaction of the alkali steels. In this detailed research study, we report the syntheses and crystal frameworks of 6 fused oxazolidine bikes and 22 complexes with FOX ligands. Reactions of these metal ions with chiral FOX ligands bring about the development of chiral complexes. Abdominal initio computational studies have made tremendous development in explaining the actions of molecular stimulants and crystalline variations of heterogeneous stimulants, yet except amorphous heterogeneous stimulants. The central problems are that the amorphous support offers unidentified satiated disordered structure, metal atoms attach to different surface area implanting sites at different rates, and the resulting implanted sites have different activation and catalytic reaction kinetics. Characteristics are elaborately linked with task and selectivity when it pertains to catalysis, as noted for circumstances in the chemical principles of induced fit and allostery, and yet the range of motions heterogeneous catalytic sites have the ability to go through is inadequately recognized. The outcomes are contrasted with the study of the analogous homoleptic complicated in the crystalline state, highlighting the influences that appear framework may have on the characteristics of supported complexes. Rotate- phonon combining plays an essential duty in molecular qubits and single-molecule magnets. To conclude, this work spectroscopically exposes and quantitates the spin- phonon couplings in regular shift metal complexes and sheds light on the beginning of the spin- phonon complexity.

Please keep in mind that the text is machine-generated by the Brevi Technologies’ Natural language Generation model, and we do not bear any responsibility. The text above has not been edited and/or modified in any way.

Source texts:

Zenodo — summary generated by Brevi Assistant

Department of Chemistry, Manonmanium Sundaranar University, Abishekapatti, Tirunelveli-627 012, Tamilnadu, India. All the systems have MAB, MAB 2 or MAB 2 types of Schiff base complexes. Department of Chemistry, University of Delhi, Delhi-110 007, India. Studies on ternary complexes or bivalent metal ions viz. Department of Chemistry, Manonmaniam Sundaranar University, Tirunelveli-627 012, Tamilnadu, India. The outcomes demonstrate the tridentate binding of the Schitf base ligand and cobalt and nickel. Cl 295A, Indira Nagar, Kanpur-208 026, Uttar Pradesh, India. In this paper, efforts have been made to explain a few examples of Cu I, Cu ll, Ru II, Zn II and other metal complexes making use of electrochemical, chemical and light-driven molecular motions. Chemical Laboratories, P. N. College Campus, Kanpur-208 001, Uttar Pradesh, India. It is discovered that in steels, other than Cu II in which phenoxy oxygen and one from carboxylato team is involved, both the oxygen atoms of the carboxylato group participate in bonding. Department of Chemistry, University of Calicut, Calicut-673 635, Kerala, India. Thiazolylazo derivatives of 3 β-diketoncs in which the dikcto function is attached directly to olefinic linkagc.

Please keep in mind that the text is machine-generated by the Brevi Technologies’ Natural language Generation model, and we do not bear any responsibility. The text above has not been edited and/or modified in any way.

Source texts:

Brief Info about Brevi Assistant

The Brevi assistant is a novel way to automatically summarize, assemble, and consolidate multiple text documents, research papers, articles, publications, reports, reviews, feedback, etc., into one compact abstractive form.

At Brevi Assistant, we integrated the most popular open-source databases to empower Researchers, Teachers, and Students to find relevant Contents/Abstracts and to always be up to date about their fields of interest.

Also, users can automate the topics and sources of interest to receive weekly or monthly summaries.

--

--

--

Brevi assistant is the world’s first AI technology able to summarize various document types about the same topic with complete accuracy.

Love podcasts or audiobooks? Learn on the go with our new app.

Recommended from Medium

The Annotated Hodgkin & Huxley: A Readers Guide

Scientifically Proven? We know you’re lying.

“Solid-State Battery” Science-Research, November 2021 — summary from PubMed and Springer Nature

“Holographic” Science-Research, January 2022, Week 3 — summary from Arxiv, DOAJ and PubMed

The Good News/Bad News of Nanotechnology In The Fields Of Environmental, Energy And Medical…

manufacturing plant

Cybernetics for the Real World

“Bone Cells” Science-Research, October 2021, Week 2 — summary from Europe PMC, PubMed and NCBI Gene

“Isotopes ” Science-Research, March 2022, Week 4 — summary from PubMed, Springer Nature, Wiley…

Get the Medium app

A button that says 'Download on the App Store', and if clicked it will lead you to the iOS App store
A button that says 'Get it on, Google Play', and if clicked it will lead you to the Google Play store
Brevi Assistant

Brevi Assistant

Brevi assistant is the world’s first AI technology able to summarize various document types about the same topic with complete accuracy.

More from Medium

Elitzur Vaidman bomb experiment

What NASA Brings Back To Earth

Pendulum experiment

CIA espionage missions rely on spy satellites